About this Journal

Online ISSN: 1521-3773    Print ISSN: 1433-7851
Angewandte Chemie
Volume 39, Issue 22, 2000.

© 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

 

PDF  3945  Cover Picture
Nguyet T. Tran, Douglas R. Powell, Lawrence F. Dahl

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<3945::AID-ANIE3945>3.0.CO;2-A

 Review
 
PDF  3964-4002  Fischer Carbene Complexes as Chemical Multitalents: The Incredible Range of Products from Carbenepentacarbonylmetal ,-Unsaturated Complexes
Armin de Meijere, Heiko Schirmer, Michael Duetsch

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<3964::AID-ANIE3964>3.0.CO;2-C

PDF  4004-4032  Piezoelectric Mass-Sensing Devices as Biosensors - An Alternative to Optical Biosensors?
Andreas Janshoff, Hans-Joachim Galla, Claudia Steinem

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4004::AID-ANIE4004>3.0.CO;2-2

 Highlight
 
PDF  4033-4036  New Developments in the Origins of the Homochirality of Biologically Relevant Molecules
Helmut Buschmann, Richard Thede, Detlef Heller

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4033::AID-ANIE4033>3.0.CO;2-2

PDF  4036-4038  The Wanzlick Equilibrium
Volker P. W. Böhm, Wolfgang A. Herrmann

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4036::AID-ANIE4036>3.0.CO;2-L

 Correspondence
 
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 4039-4040  Comments on the Terminology for Applications of Temporarily Attached Solubility-Modifying Moieties in Combinatorial Chemistry
Andreas Link

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4039::AID-ANIE4039>3.0.CO;2-3

 Communication
 
PDF  4041-4045  Inorganic Layered Double Hydroxides as Nonviral Vectors
Jin-Ho Choy, Seo-Young Kwak, Yong-Joo Jeong, Jong-Sang Park

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4041::AID-ANIE4041>3.0.CO;2-C

PDF  4045-4047  Epoxidation Catalysis by a Manganese Corrole and Isolation of an Oxomanganese(v) Corrole
Zeev Gross, Galina Golubkov, Liliya Simkhovich

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4045::AID-ANIE4045>3.0.CO;2-P

PDF  4048-4051  Structural, Electrochemical, and Photophysical Properties of Gallium(iii) 5,10,15-Tris(pentafluorophenyl)corrole
Jesper Bendix, Ivan J. Dmochowski, Harry B. Gray, Atif Mahammed, Liliya Simkhovich, Zeev Gross

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4048::AID-ANIE4048>3.0.CO;2-7

PDF  4051-4053  Evidence for the Formation of a RuIII-RuIII Bond in a Ruthenium Corrole Homodimer
François Jérôme, Béatrice Billier, Jean-Michel Barbe, Enrique Espinosa, Slimane Dahaoui, Claude Lecomte, Roger Guilard

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4051::AID-ANIE4051>3.0.CO;2-A

PDF  4053-4055  A Triangular Triplatinum Complex with Electron-Releasing SiPh2 and PMe3 Ligands: [{Pt(-SiPh2)(PMe3)}3]
Kohtaro Osakada, Makoto Tanabe, Tomoaki Tanase

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4053::AID-ANIE4053>3.0.CO;2-Z

PDF  4055-4058  Synthesis of a Versatile Tridentate Anthracene Ligand and its Application for the Synthesis of Hypervalent Pentacoordinate Boron Compounds (10-B-5)
Makoto Yamashita, Yohsuke Yamamoto, Kin-ya Akiba, Shigeru Nagase

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4055::AID-ANIE4055>3.0.CO;2-N

PDF  4058-4061  Diels-Alder Type Addition of 1,3-Dienes to a Disulfide Bridging Ligand in Diruthenium Complexes
Hiroyasu Sugiyama, Yong-Shou Lin, Kazuko Matsumoto

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4058::AID-ANIE4058>3.0.CO;2-5

PDF  4061-4063  Regiospecific Hydride Transfer from cis-[Ru(bpy)2(CO)(CHO)]+ to NAD+ Model Compounds: A Model for Enzymatic Reactions by Aldehyde Dehydrogenases
Hideo Konno, Kazuhiko Sakamoto, Osamu Ishitani

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4061::AID-ANIE4061>3.0.CO;2-8

PDF  4063-4067  A New Self-Assembling System for Targeted Gene Delivery
Michael A. W. Eaton, Terence S. Baker, Catherine F. Catterall, Kenneth Crook, Graham S. Macaulay, Barbara Mason, Timothy J. Norman, David Parker, Justin J. B. Perry, Richard J. Taylor, Alison Turner, A. Neil Weir

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4063::AID-ANIE4063>3.0.CO;2-X

PDF  4067-4070  A Versatile Periodate-Coupled Fluorogenic Assay for Hydrolytic Enzymes
Fabrizio Badalassi, Denis Wahler, Gérard Klein, Paolo Crotti, Jean-Louis Reymond

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4067::AID-ANIE4067>3.0.CO;2-9

PDF  4070-4073  Formation of a Giant Supramolecular Porphyrin Array by Self-Coordination
Kazuya Ogawa, Yoshiaki Kobuke

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4070::AID-ANIE4070>3.0.CO;2-C

PDF  4073-4075  Enantioselective Total Synthesis of (+)-Gelsemine: Determination of Its Absolute Configuration
Satoshi Yokoshima, Hidetoshi Tokuyama, Tohru Fukuyama

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4073::AID-ANIE4073>3.0.CO;2-V

PDF  4076-4079  (-)-Rhizochalin is a Dimeric Enantiomorphic (2R)-Sphingolipid: Absolute Configuration of Pseudo-C2v-Symmetric Bis-2-amino-3-alkanols by CD
Tadeusz F. Molinski, Tatyana N. Makarieva, Valentin A. Stonik

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4076::AID-ANIE4076>3.0.CO;2-D

PDF  4079-4082  Amphoteric Character of 2-Vinyloxiranes: Synthetic Equivalents of ,-Unsaturated Aldehydes and a Vinylogous Enolate
Mark Lautens, Stéphane G. Ouellet, Stéphane Raeppel

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4079::AID-ANIE4079>3.0.CO;2-W

PDF  4082-4084  Total Synthesis of (+)-Eurylene and (+)-14-Deacetyleurylene
Yoshiki Morimoto, Koji Muragaki, Toshiyuki Iwai, Yukio Morishita, Takamasa Kinoshita

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4082::AID-ANIE4082>3.0.CO;2-Z

PDF  4084-4088  Cuprophilicity: Spectroscopic and Structural Evidence for Cu-Cu Bonding Interactions in Luminescent Dinuclear Copper(i) Complexes with Bridging Diphosphane Ligands
Chi-Ming Che, Zhong Mao, Vincent M. Miskowski, Man-Chung Tse, Chi-Keung Chan, Kung-Kai Cheung, David Lee Phillips, King-Hung Leung

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4084::AID-ANIE4084>3.0.CO;2-N

PDF  4088-4090  Low-Temperature Activation of Dioxygen and Hydrocarbon Oxidation Catalyzed by a Phosphovanadomolybdate: Evidence for a Mars-van Krevelen Type Mechanism in a Homogeneous Liquid Phase
Alexander M. Khenkin, Ronny Neumann

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4088::AID-ANIE4088>3.0.CO;2-#

PDF  4090-4092  Oxidosqualene Cyclase Residues that Promote Formation of Cycloartenol, Lanosterol, and Parkeol
Michelle M. Meyer, Michael J. R. Segura, William K. Wilson, Seiichi P. T. Matsuda

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4090::AID-ANIE4090>3.0.CO;2-8

PDF  4093-4095  A New Efficient Synthesis of (R,R)-2,2-Bipyrrolidine: An Interesting Chiral 1,2-Diamine with C2 Symmetry
Alexandre Alexakis, Axel Tomassini, Cyril Chouillet, Sylvain Roland, Pierre Mangeney, Gerald Bernardinelli

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4093::AID-ANIE4093>3.0.CO;2-R

PDF  4096-4098  Isolation of a Pyridinium Alkoxy Ion Bridged Dimeric Zinc Complex for the Coupling Reactions of CO2 and Epoxides
Hoon Sik Kim, Jai Jun Kim, Byung Gwon Lee, Ok Sang Jung, Ho Gyeom Jang, Sang Ook Kang

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4096::AID-ANIE4096>3.0.CO;2-9

PDF  4098-4101  Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral CoIII, Square-Planar PdII, and Linear AuI or AgI Ions
Takumi Konno, Yu Chikamoto, Ken-ichi Okamoto, Tadashi Yamaguchi, Tasuku Ito, Masakazu Hirotsu

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4098::AID-ANIE4098>3.0.CO;2-Y

PDF  4101-4104  Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of 31.1
My-Hang V. Huynh, Peter S. White, Thomas J. Meyer

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4101::AID-ANIE4101>3.0.CO;2-E

PDF  4104-4106  The First Highly Enantioselective Rh-Catalyzed Enyne Cycloisomerization
Ping Cao, Xumu Zhang

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4104::AID-ANIE4104>3.0.CO;2-X

PDF  4106-4108  Rhodium-Mediated Asymmetric Hydroformylation with a Novel Bis(diazaphospholidine) Ligand
Simon Breeden, David J. Cole-Hamilton, Douglas F. Foster, Gary J. Schwarz, Martin Wills

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4106::AID-ANIE4106>3.0.CO;2-L

PDF  4108-4110  arachno-[Sn8]6- or closo-[Li2Sn8]4-? Synthesis and Characterization of A4Li2Sn8 (A=Rb, K)
Svilen Bobev, Slavi C. Sevov

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4108::AID-ANIE4108>3.0.CO;2-9

PDF  4111-4114  Reductive Samariation of Anomeric 2-Pyridyl Sulfones with Catalytic Nickel: An Unexpected Improvement in the Synthesis of 1,2-trans-Diequatorial C-Glycosyl Compounds
Nicolas Miquel, Gilles Doisneau, Jean-Marie Beau

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4111::AID-ANIE4111>3.0.CO;2-C

PDF  4114-4116  Formation of Optically Active Aromatic -Amino Acids by Catalytic Enantioselective Addition of Imines to Aromatic Compounds
Steen Saaby, Xiangming Fang, Nicholas Gathergood, Karl Anker Jørgensen

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4114::AID-ANIE4114>3.0.CO;2-V

PDF  4117-4118  Hydrogen/Deuterium Exchange Catalyzed by an Unusually Stable Mercury-Toluene Complex
Alexander S. Borovik, Simon G. Bott, Andrew R. Barron

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4117::AID-ANIE4117>3.0.CO;2-D

PDF  4119-4121  Stabilization of a Reactive Cationic Species by Supramolecular Encapsulation
Marco Ziegler, Julia L. Brumaghim, Kenneth N. Raymond

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4119::AID-ANIE4119>3.0.CO;2-1

PDF  4121-4125  Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three-Shell 145-Atom Metal-Core Geometry of Pseudo Icosahedral Symmetry
Nguyet T. Tran, Douglas R. Powell, Lawrence F. Dahl

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4121::AID-ANIE4121>3.0.CO;2-A

PDF  4127-4130  A Novel CSiP Ring from the Reaction of a Complexed Phosphinidene and a Silene
Mark J. M. Vlaar, Andreas W. Ehlers, Frans J. J. de Kanter, Marius Schakel, Anthony L. Spek, Martin Lutz, Nadejda Sigal, Yitzhak Apeloig, Koop Lammertsma

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B

PDF  4130-4133  Virtual Screening for Bioactive Molecules by Evolutionary De Novo Design
Gisbert Schneider, Odile Clément-Chomienne, Laurence Hilfiger, Petra Schneider, Stefan Kirsch, Hans-Joachim Böhm, Werner Neidhart

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4130::AID-ANIE4130>3.0.CO;2-E

PDF  4133-4136  Chirally Modified n-Butyllithium: Tuning the Composition, Structure, and Enantioselectivity with Modular Fencholates
Bernd Goldfuss, Melanie Steigelmann, Frank Rominger

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4133::AID-ANIE4133>3.0.CO;2-X

PDF  4136-4139  C-H Activation by Direct Borane-Hydrocarbon Dehydrogenation: Kinetic and Thermodynamic Aspects
Bernd Goldfuss, Paul Knochel, Lars O. Bromm, Kolja Knapp,

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4136::AID-ANIE4136>3.0.CO;2-F

PDF  4139-4142  Multilevel Molecular Electronic Species: Electrochemical Reduction of a [2?] CoII4 Grid-Type Complex by 11 Electrons in 10 Reversible Steps
Mario Ruben, Esther Breuning, Jean-Paul Gisselbrecht, Jean-Marie Lehn

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4139::AID-ANIE4139>3.0.CO;2-Y

PDF  4142-4145  Repetitive Application of Perfluoro-Tagged Pd Complexes for Stille Couplings in a Fluorous Biphasic System
Siegfried Schneider, Willi Bannwarth

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4142::AID-ANIE4142>3.0.CO;2-0

PDF  4145-4148  A Li10 Cage Containing the [C6H11P-C(Ph)-N]2- Ion: Umpolung in the Oligomerization of a Nitrile
Neil Feeder, Yvonne G. Lawson, Paul R. Raithby, Jeremy M. Rawson, Alexander Steiner, Jody A. Wood, Anthony D. Woods, Dominic S. Wright

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4145::AID-ANIE4145>3.0.CO;2-J

PDF  4148-4150  Stabilization of a Pentastibacyclopentadienyl Ligand in the Triple-Decker Sandwich Complexes [{(5-1,2,4-tBu3C5H2)Mo}2(,5-Sb5)] and [(5-1,2,4-tBu3C5H2)Mo(,5-Sb5)Mo(5-1,4-tBu2-2-MeC5H2)]
Hans Joachim Breunig, Neil Burford, Roland Rösler

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4148::AID-ANIE4148>3.0.CO;2-1

PDF  4150-4153 
Alla Zamyatina, Sabine Gronow, Clemens Oertelt, Michael Puchberger, Helmut Brade, Paul Kosma

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4150::AID-ANIE4150>3.0.CO;2-A

PDF  4153-4155  A New Highly Efficient Catalyst System for the Coupling of Nonactivated and Deactivated Aryl Chlorides with Arylboronic Acids
Alexander Zapf, Andreas Ehrentraut, Matthias Beller

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4153::AID-ANIE4153>3.0.CO;2-T

PDF  4156-4158  A Palladium-Catalyzed Synthesis of Amidines from Aryl Halides
C. Gustaf Saluste, Richard J. Whitby, Mark Furber

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4156::AID-ANIE4156>3.0.CO;2-B

PDF  4158-4160  Cobalt on Charcoal: A Convenient and Inexpensive Heterogeneous Pauson-Khand Catalyst
Seung Uk Son, Sang Ick Lee, Young Keun Chung

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4158::AID-ANIE4158>3.0.CO;2-#

PDF  4160-4162  (CuI)2P8Se3: An Adduct of D3-Symmetrical P8Se3 Cage Molecules with Cu2I2 Rhomboids
Arno Pfitzner, Sara Reiser, Tom Nilges

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4160::AID-ANIE4160>3.0.CO;2-8

PDF  4162-4163  The Structure of the FeIVO44- Ion
Mark T. Weller, Andrew L. Hector

Published Online: 14 Nov 2000
DOI10.1002/1521-3773(20001117)39:22<4162::AID-ANIE4162>3.0.CO;2-X



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